Let $X_i$ be iid random discrete variables with pmf $f$ .
We may restrict ourselve to pmfs with finite even support: $f \in G_N$ ($ f[k] > 0 \implies |k| \le N$) or perhaps $f \in G^{+}_N$ ($ f[k] > 0 \iff |k| \le N$) .
I wonder if there is some characterization on $f$ (perhaps sufficient or necesary conditions) for this property to hold:
$$P(X_1 + \cdots X_{n+1} = 0) < P(X_1 + \cdots X_n = 0) \, \forall n\ge 1$$
Alternatively, letting $f^{(n)}$ denote the $n-$self convolution of $f$, the above is equivalent to $f^{(n+1)}[0] < f^{(n)}[0] $
In by this question it's shown that $f \in G^{+}_1$ is not enough, but $g=f^{(2)}$ is.