"if someone does not mind to expose another way"...
Though nothing is mentioned in the statement about this, I will assume the matrices considered have entries in a field$~F$ that is not of characteristic$~2$ (in other words $1$ and $-1$ are distinct elements in $F$), since the statement is false for matrices with entries in a field of characteristic$~2$.
The set of $n\times n$ matrices with entries in $F$ is (with usual addition and scalar multiplication) a vector space $V$ over$~F$, and the operation of transposition defines a linear map $T:V\to V$. Since $T\circ T=I$, the polynomial $X^2-1=(X-1)(X+1)\in F[X]$ is an annihilating polynomial of $T$. Since this polynomial, which is split as indicated, has distinct roots $1$ and $-1$ in $F$, the operator $T$ is diagonalisable with eigenvalues in $\{1,-1\}$. This means that the sum of the two eigenspaces $V_\lambda$ for $\lambda=1$ and $\lambda=-1$, which is a direct sum, fills the whole space: $V=V_1\oplus V_{-1}$. But $V_1$ is the subspace of matrices $M$ satisfying $T(M)=M$, in other words of symmetric matrices, and similarly $V_{-1}$ is the subspace of anti-symmetric matrices.
The fact that $V=V_1+V_{-1}$ says that every matrix in $V$ can be written as sum of a symmetric and an anti-symmetric matrix (that was the question); moreover the fact that the sum is direct says that they can be so written in a unique manner.