Start by restating the problem with a different choice of variables:
we seek to show that
$${n\choose k}
= \sum_{p=0}^{3k} {n\choose 3k-p} (-1)^p
\sum_{q=0}^p {n\choose q} {q\choose p-q}.$$
Re-write the sum as
$$\sum_{q\ge 0} {n\choose q}
\sum_{p\ge q} {n\choose 3k-p} (-1)^p {q\choose p-q}.$$
Introduce the integral representation
$${n\choose 3k-p}
= \frac{1}{2\pi i}
\int_{|z|=\epsilon} \frac{(1+z)^n}{z^{3k-p+1}} \; dz$$
This yields for the inner sum that
$$\sum_{p\ge q} {n\choose 3k-p} (-1)^p {q\choose p-q}
= \frac{1}{2\pi i}
\int_{|z|=\epsilon} \frac{(1+z)^n}{z^{3k+1}}
\sum_{p\ge q} {q\choose p-q} (-1)^p z^p \; dz.$$
The sum remaining in the integral is
$$\sum_{p\ge q} {q\choose p-q} (-1)^p z^p
= \sum_{p\ge 0} {q\choose p} (-1)^{p+q} z^{p+q}
\\ = (-1)^q z^q \sum_{p\ge 0} {q\choose p} (-1)^p z^q
= (-1)^q z^q (1-z)^q.$$
This yields for the inner sum the integral
$$\frac{1}{2\pi i}
\int_{|z|=\epsilon} \frac{(1+z)^n}{z^{3k+1}}
(-1)^q z^q (1-z)^q \; dz.$$
To conclude substitute this into the outer sum that we seek to
evaluate to get
$$\frac{1}{2\pi i}
\int_{|z|=\epsilon} \frac{(1+z)^n}{z^{3k+1}}
\sum_{q\ge 0} {n\choose q}(-1)^q z^q (1-z)^q \; dz
\\ = \frac{1}{2\pi i}
\int_{|z|=\epsilon} \frac{(1+z)^n}{z^{3k+1}}
(1-z(1-z))^n\; dz.$$
Note that $(1+z)\times (1-z\times (1-z)) = 1 + z^3$ so this becomes
$$\frac{1}{2\pi i}
\int_{|z|=\epsilon} \frac{(1+z^3)^n}{z^{3k+1}} \; dz$$
To conclude observe that
$$[z^{3k}] (1+z^3)^n = {n\choose k}.$$
A trace as to when this method appeared on MSE and by whom starts at this
MSE link.