It is perhaps better to to get used to integral curvature as a unit of solid angle in its own right by virtue of its inseparable definition / association with Gauss curvature.
If it were asked to explain
the equivalence of length between integrating over the arc of a unit circle ( radius in the plane $R=1$ ) and integrating over the subtended ( spanning plane) angle $\theta $,
an answer would be like:
$$ s_2-s_1= \int_{s1}^{s2} ds= \int_{\theta_1}^{\theta_2}R d \theta =\int_{\theta_1}^{\theta_2}\frac{ d \theta }{\kappa}= \frac{\theta_2-\theta_1}{\kappa}= (\theta_2-\theta_1) R $$
Angles can be summed or difference found from end of arc to end of arc.
Your question in other words is
to explain the equivalence of patch area between integrating over the surface of a unit sphere ( radius of spherical patch R =1 ) and integrating over the covering / surrounding (solid) angle.
Element of solid angle is $ K dA = d\Omega$ and lumped/integrated dimensionless solid angle ( K= Gaussian curvature) is $ \Omega= \int K \;dA$ termed Integral Curvature by Gauss and measured in units of steradians...
It is $\pi $ for an octant, $ 2 \pi$ for a hemisphere, $ 4 \pi \; $ for a full sphere, $- 4 \pi $ for a full pseudosphere and so on.
$$ A_2-A_1= \int_{A_2}^{A_1} \frac{K dA }{K}=\int_{\Omega_2}^{\Omega_1} \frac{d \Omega }{K}=\int_{\Omega_2}^{\Omega_1} R^2 {d \Omega } = (\Omega_2- \Omega_1) R^2$$
Solid angles can be summed or difference found when common triangular areas of common sphere center vertex are merged.
Whereas an angle is defined as spanned between 2 arms in Euclidean geometry of the plane, a solid angle is spanned among 3 planes with three dihedral angles pairwise between them.
In spherical trigonometry on unit sphere we consider a spherical triangular patch enclosed between intersected segments of a great circle and two longitudes making 3 dihedral angles $(A,B,C)$ has enclosed area
$$ \text{ Integral Curvature = Spherical Deficit } = (A+B+C-\pi) $$
derived from the Gauss-Bonnet theorem.