Enumerate the rational numbers $q_i$. Place an open ball $B_i$ of radius $3^{-i}$ about $q_i$. We will construct an explicit real number $\alpha$ that does not lie in the union of the balls.
We will define a sequence $c_n\in\{0,2\}$ and set $$\alpha=2\sum_{n=1}^{\infty}\frac{c_n}{3^{n}}.$$
This sum clearly converges as it is Cauchy.
Consider the interval $[0,2]$. After removing the ball about $q_1$ we are left with either the interval $[0,\frac23]$, or $[\frac43,2]$. In the former case we set $c_1=0$ and in the latter case we set $c_1=2$. If both are free from the ball, we can default to $c_1=0$.
Either way, the interval $$I_1=\left[2\sum_{n=1}^{1}\frac{c_n}{3^{n}}, 2\sum_{n=1}^{1}\frac{c_n}{3^{n}}+\frac2{3^1}\right]$$ is disjoin from the open ball $B_1$.
Now suppose we have chosen $c_1,c_2,\cdots,c_m$ such that the open balls $B_1,\cdots,B_m$ are disjoint from the interval:
$$I_m=\left[2\sum_{n=1}^{m}\frac{c_n}{3^{n}}, 2\sum_{n=1}^{m}\frac{c_n}{3^{n}}+\frac2{3^m}\right]$$
Then $B_{m+1}$ will be disjoint from: $$I_{m+1}=\left[2\sum_{n=1}^{m+1}\frac{c_n}{3^{n}}, 2\sum_{n=1}^{m+1}\frac{c_n}{3^{n}}+\frac2{3^{m+1}}\right]$$
for either $c_{m+1}=0$ or $c_{m+1}=2$. In simple terms, all this is saying is that in the worst case removing $B_{m+1}$ removes the middle third of $I_m$, so we always have the left or right third of $I_m$ disjoint from $B_{m+1}$.
We obtain upper and lower bounds for $\alpha$ by replacing all $c_n, n>m$ with $2$ or $0$ respectively. Thus $\alpha\in I_m$ for all $m$. Thus $\alpha\notin B_m$ for all $m$ as required.