This is a partial answer about generating the matrices with the conjectured minimum eigenvalues, but does not show that they are minimum for these matrices, or that there can't be other matrices with smaller eigenvalues.
Sufficient conditions for the conjectured $\lambda _{\min }$ to be an
eigenvalue
For $n$ odd
We first define two sets: $U$ has the diagonal entry $b^{n}$ and the $(n-1)/2 $ smallest entries, and $V$ has the others.
$$
U=\left\{ b^{n},(b-1),\ldots (b-1)b^{(n-1)/2-1}\right\} ,~V=\left\{
(b-1)b^{(n-1)/2},\ldots ,(b-1)b^{n-1}\right\},
$$
for which
\begin{align}
S_{U} &=\sum_{i\in U}i=b^{n}+b^{(n-1)/2}-1 \\
S_{V} &=\sum_{i\in V}i=b^{n}-b^{(n-1)/2} \\
S_{U}-S_{V} &=2b^{(n-1)/2}-1=\lambda _{\min }
\end{align}
Let $\alpha $ and $\beta $ be two index sets, disjoint with union $\{1,\ldots ,n+1\}$ and $\left\vert \alpha \right\vert =\left\vert \beta \right\vert =(n+1)/2$. We construct a matrix with an eigenvector for $\lambda _{\min }$ having $\alpha $-indexed entries $+1$ and $\beta $-indexed entries $-1$. For a row in the matrix with row index in $\alpha $ the entries with column indices in $\alpha $ have the entries of $U$ in some order that has $b^{n}$ on the diagonal, and the entries with column indices in $\beta $ have the entries of $V$ in some order. Then multiplying this row with the eigenvector gives
$$
S_{U}(+1)+S_{V}(-1)=\lambda _{\min }(+1)
$$
which satisfies the eigenvalue/eigenvector requirement.
For a row in the matrix with row index in $\beta $ the entries with column indices in $\beta $ have the entries of $U$ in some order that has $b^{n}$ on the diagonal, and the entries with column indices in $\alpha $ have the
entries of $V$ in some order. Then multiplying this row with the eigenvector gives
$$
S_{V}(+1)+S_{U}(-1)=\lambda _{\min }(-1)
$$
which also satisfies the requirement, and we have found an eigenvector for $\lambda_{\min}$. In other words, we could permute rows and columns to give $2\times 2$ block form with rows from $U$ in the diagonal blocks and rows from $V$ in the
off-diagonal blocks; the eigenvector then has its first-half entries $+1$ and second-half entries $-1$ (or vice-versa, which is just a scalar multiple).
(There are some circulant matrices when $\alpha $ has odd indices and $\beta$ has even indices.)
For $n$ even
We define four sets: $W$ has the diagonal entry $b^{n}$ and the $n/2-1$ smallest entries, and $X$ has the $n/2+1$ others; $Y$ has the diagonal entry $b^{n}$ and the $n/2$ smallest entries, and $Z$ has the $n/2$ others:
\begin{align}
W &=\left\{ b^{n},(b-1),\ldots (b-1)b^{n/2-2}\right\} ,~X=\left\{
(b-1)b^{n/2-1},\ldots ,(b-1)b^{n-1}\right\} \\
Y &=\left\{ b^{n},(b-1),\ldots (b-1)b^{n/2-1}\right\} ,~Z=\left\{
(b-1)b^{n/2},\ldots ,(b-1)b^{n-1}\right\}
\end{align}
for which
\begin{align}
S_{W} &=\sum_{i\in W}i=b^{n}+b^{n/2-1}-1 \\
S_{X} &=\sum_{i\in X}i=b^{n}-b^{n/2-1} \\
S_{Y} &=\sum_{i\in Y}i=b^{n}+b^{n/2}-1 \\
S_{Z} &=\sum_{i\in Z}i=b^{n}-b^{n/2}
\end{align}
Let $\alpha $ and $\beta $ be two index sets, disjoint with union $\{1,\ldots ,n+1\}$ and $\left\vert \alpha \right\vert =n/2$, $\left\vert
\beta \right\vert =n/2+1$. We construct a matrix with an eigenvector for $\lambda _{\min }$ having $\alpha$-indexed entries $(b^{n}-b^{n/2-1})$ and $\beta$-indexed entries $-(b^{n}-b^{n/2})$. For a row in the matrix with row index in $\alpha $ the entries with column indices in $\alpha $ have the entries of $W$ in some order that has $b^{n}$ on the diagonal, and the entries with column indices in $\beta $ have the entries of $X$ in some order. Then multiplying this row with the eigenvector gives
$$
S_{W}(b^{n}-b^{n/2-1})+S_{X}(-(b^{n}-b^{n/2}))=\lambda _{\min
}(b^{n}-b^{n/2-1})
$$
which satisfies the requirement.
For a row in the matrix with row index in $\beta $ the entries with column indices in $\beta $ have the entries of $Y$ in some order that has $b^{n}$ on the diagonal, and the entries with column indices in $\alpha $ have the entries of $Z$ in some order. Then multiplying this row with the eigenvector gives
$$
S_{Z}(b^{n}-b^{n/2-1})+S_{Y}(-(b^{n}-b^{n/2}))=\lambda _{\min
}(-(b^{n}-b^{n/2}))
$$
which also satisfies the requirement, and we have found an eigenvector for $\lambda_{\min}$.