For the equation (IITJEE-M-Jan-2023) $$\tan^{-1}\frac{2x}{1-x^2}+\cot^{-1} \frac{1-x^2}{2x}=\frac{\pi}{3},\tag{1}$$ usually, two roots: $-1/\sqrt{3}$ and $2-\sqrt{3}$ belonging to $[-1,1]$ are found and discussed. We show two more roots here.
Case$(1)$ $x<-1$: Both the arguments in $(1)$ are positive so we can re-write it as $$2\tan^{-1}\frac{2x}{1-x^2}=\frac{\pi}{3}\implies x^2+2\sqrt{3}x-1=0 $$ giving us two root $x=-2\pm \sqrt{3}$, here we choose $x=-2-\sqrt{3}.$
Case (2) $x>1$: We can re-write $(1)$ as $$\tan^{-1} \frac{2x}{1-x^2}+\pi+\tan^{-1}\frac{2x}{1-x^2}=\frac{\pi}{3}$$ $$\implies 4 \tan^{-1} x-2\pi+\pi=\frac{\pi}{3}\implies \tan^{-1}x=\frac{\pi}{3}.$$
So we get $x=\sqrt{3}$.
The question is whether Eq. $(1)$ has other root(s)?
Edit Also see Why $\cot^{-1}x$ is an odd function in Mathematica
