Coming from here and the Wikipedia page on conservative extension, which defines a proof-theoretic conservative extension like this:
a theory $T_2$ is a (proof theoretic) conservative extension of a theory $T_1$ if every theorem of $T_1$ is a theorem of $T_2$, and any theorem of $T_2$ in the language of $T_1$ is already a theorem of $T_1$.
And a model-theoretic conservative extension as this:
an extension $T_2$ of a theory $T_1$ is model-theoretically conservative if $T_{1}\subseteq T_{2}$ and every model of $T_{1}$ can be expanded to a model of $T_{2}$.
From the Wiki and the linked question, I gather that model theoretic conservative extensions are a subset of proof-theoretic conservative extensions. But the question that keeps bugging me is what is a (preferably constructible,) example of a proof-theoretic conservative extension that is not also model-theoretic conservative extension? What would that look like?