For the case $n = 4$, it is easy to see that there are $15$ equally probable outcomes in which at least $1$ head is obtained. (The sole outcome that is excluded is $TTTT$.) Among these $15$ outcomes, in order for the number of heads to be a multiple of $3$, there must be exactly $3$ heads. This occurs in one of four ways:
$$HHHT, HHTH, HTHH, THHH.$$ So, given that at least one head is obtained, the desired probability is $4/15$, not $1/3$. This excludes choice (A). Note that when $n = 4$, choices (B) and (C) yield the correct probability, so we cannot eliminate these yet.
The natural thing to do is to extend the above reasoning to $n = 5$, since (B) and (C) are not equivalent in this case. So there are $2^5 - 1 = 31$ outcomes in which at least $1$ head is obtained. Of these, we again require exactly $3$ heads, since we cannot have $0$ or $6$ heads.
The number of such outcomes with exactly $3$ heads is $\binom{5}{3} = 10$. Explicitly, they are:
$$HHHTT, HHTHT, HHTTH, HTHHT, HTHTH, \\
HTTHH, THHHT, THHTH, THTHH, TTHHH.$$
So the desired probability is $10/31$, which is consistent with choice (C). However, we have not proven that (D) is the answer, because we have only looked at two specific cases. We would need to prove that (C) is true for all integer $n \ge 4$.
I leave the details of such a proof as an exercise; however, I will provide some hints based on the simple cases illustrated above.
- In general, the number of outcomes with at least one head is obviously $2^n - 1$.
- The number of outcomes in which the number of heads is a multiple of $3$ (and is strictly greater than $0$) is $$\binom{n}{3} + \binom{n}{6} + \cdots + \binom{n}{3m},$$ where $m$ is the largest positive integer for which $3m \le n$.