There are exact solutions provided already, however, I will present a way to estimate the answer to the first question.
Note that the question asks about the number of rolls until the cumulative sum is "more than k" which means we stop if and only if we exceed k (we will still roll if our cumulative sum so far is exactly k).
We can see that if we are at the cumulative sum = k, the possible outcomes on the one final die roll are $1, 2, 3, 4, 5$ or $6$ which will increase our cumulative sum to $k+1, k+2, k+3, k+4, k+5$ or $k+6$. Call these as our prospective stopping points. Note that $k+6$ is also a stopping point since if we are at the sum = $k$ and get $6$ on our final die roll our sum gets to $k+6$ and then we stop rolling. The question says "....more than $k$, " meaning our first stopping point is $k+1$ instead of $k$. If we were stopping at sum = $k$ then the maximum stopping point would have been $(k - 1) + 6 = k + 5$
We know those stopping points have the respective probabilities of $6/21, 5/21, 4/21, 3/21, 2/21$ and $1/21$ (source: https://math.stackexchange.com/a/12553/1204464).
Therefore, our expected stopping point (or the cumulative sum at which we are expected to stop) is given by:
$$(k+1)*\frac{6}{21} + (k+2)*\frac{5}{21} + (k+3)*\frac{4}{21} + (k+4)*\frac{3}{21} + (k+5)*\frac{2}{21} + (k+6)*\frac{1}{21}$$
which comes from the definition of expected value.
Using the renewal theory result from the cited link above, we divide the above expectation by the expected value of a single die roll ($7/2$) to get the expected number of rolls needed:
$$\frac{2k}{7} + \frac{16}{21}$$ which can be re written as $$\frac{2(k+1)}{7} + \frac{10}{21}$$.
Thus, the expected number of rolls for the cumulative sum to get to at least N can be approximated by $$\frac{2N}{7} + \frac{10}{21}$$ for large values of N since the derivation in the above-cited link takes that as an assumption.
The exact solution can be found in the pdf "A Collection of Dice Problems
with solutions and useful appendices by Matthew M. Conroy" accessible from the link https://www.madandmoonly.com/doctormatt/mathematics/dice1.pdf [problem number 35].
The author there shows how close this estimate is to the actual value.