Let $\rho$ be an Hermitian matrix with unit trace (this is the context I've found this result stated in, but I don't know if these restrictions are necessary for the result). Suppose $p_i\ge0$ with $\sum_i p_i=1$, and let $U_i$ be unitaries. Consider $$\rho'= \sum_i p_i \, U_i \rho U_i^\dagger.$$ Then $\rho'\preceq \rho$, by which I mean that the vector of eigenvalues of $\rho'$ is majorized by that of $\rho$. I think this is shown in the reference "A. Uhlmann, Wiss. Z. Karl-Marx-Univ. Leipzig 20, 633 (1971)" but I could not find an English version of it.
For $p_i=\delta_{i0}$ the result is clear, as $U\rho U^\dagger$ has the same eigenvalues of $\rho$. How do you prove the general case?