As shown in this answer, if $A$ is a real skew-symmetric matrix, and $v,w$ are a pair of orthogonal singular vectors with $$Av=sw \qquad\text{ and }\qquad Aw=-sv,$$ for some $s>0$, then the corresponding eigenvectors of $A$ are $v\pm iw$ (with eigenvalues $\pm is$).
However, as discussed for example in these notes (Link to pdf), one can state more generally that for any (possibly complex) skew-symmetric $A$ there is a unitary $U$ such that $U^TAU$ is block diagonal:
$$U^T A U = \operatorname{diag}\left\{\begin{pmatrix}0 & m_1 \\ -m_1 & 0\end{pmatrix}, \begin{pmatrix}0 & m_2 \\ -m_2 & 0\end{pmatrix},..., \begin{pmatrix}0 & m_n \\ -m_n & 0\end{pmatrix},\boldsymbol0\right\}.$$ In analogy with the above statement about the real case, this can be seen as equivalent to stating that the singular vectors of $A$ can be organised as pairs $v_k,w_k$ such that $$Av_k=s_kw_k \qquad\text{ and }\qquad Aw_k^*=-s_kv_k^*.$$ However, now $v_k\pm iw_k$ aren't always eigenvectors.
Is there a general relation between eigenvectors and singular vectors in the complex case?