There's probably no precise answer to this question, since "taking a sample", "observing the occurrence of a random variable" and "performing a random experiment" are just expressions we use in reference to real life actions that we interpret as taking note of the result of an experiment (in a broad sense, i.e. a procedure) whose result we can't completely predict beforehand. For this to make sense we first need to agree on the aspect of the final result that we are interested on; and also we could discuss the cause of the uncertainty. For instance, when throwing a coin in the air we could:
- check if it eventually goes down in a reasonable amount of time (maybe a very long one, like an hour);
- check if it touches the ground in a very precise amount of time (maybe a very small interval instead of an exact number), which we could calculate using some physic's laws and given that we know the initial height and velocity;
- check if when touching the ground is heads or tails that looks upwards, maybe given that we know every detail about velocity, height, initial position, point where force is applied and the actual force, etc.;
- the same but not having all that information.
Which of these experiments are random and which are not? Well, perhaps there's no right answer. Of course, I tried to describe them from more to less predictable outcome (if we could think that is a matter of degree), but maybe we could agree that the first one is not random, while the last one is; the second might be, but the third one is difficult to actually perform, giving some chaotic dynamics involved. In fact, Bohr and Einstein had a famous controversy regarding this subject: basically, Einstein would say that the third one would not be random if we were good enough with our theories and predictions, while Bohr would say that all of them — maybe even the first one — are random.
All this is just to explain that there's no clear notion — even less a definition — of what "random" means. In a sense, is just a consequence of our lack of knowledge or imprecision, although it could also be a fundamental characteristic of the universe and the way it works.
So when we refer to a random experiment and a random event we can look at it in two ways:
- before the experiment is performed, the event $A$ is an element of the $\sigma$-algebra $\mathcal A$, and so the value $P(A)$ is defined, where $P\colon \mathcal A\longrightarrow [0,1]$ is a function satisfying the usual properties of a probability;
- after the experiment is performed we get as result a specific element of $\Omega$, say $\omega_0$, and we say that $A$ "occured", "happened", etc., if $\omega_0\in A$, and that it didn't otherwise.
This goes all around the interpretation of probability theory, and usually there's not much formalization surrounding this, but what we can formalize is that performing a random experiment is selecting an element $\omega_0$ of the random space $\Omega$ (or maybe, letting the universe do it in a way that "respects" the probability law, whatever that means).
In the same sense, observing the value of a random variable $X$ or registering the value of an occurrence of $X$ can be represented as the value $X(\omega_0)$, where $\omega_0$ is the result of the random experiment.
And since a "random sample of size $n$" is just a collection of $n$ independent and identically distributed random variables, say
$$X_1,X_2,\ldots,X_n$$
(also representable as a random vector), "drawing a sample" is performing the experiment (*) underlying the definition of the space $(\Omega,\mathcal A,P)$ in such a way that the independence and identical distribution assumptions are valid, to obtain a result $\omega_0$. The observed sample is not a collection of random variables, but the $n$-tuple
$$\big(X_1(\omega_0),X_2(\omega_0),\ldots,X_n(\omega_0)\big) \in \mathbb R^n.$$
(*) Here, we must consider that the random experiment is, for instance, selecting $n$ persons who will answer a question, or any other action that results in $n$ results/elements of $\Omega$.
It is true that we could also think that there's only one variable $X$ defined on the space and that we perform the experiment $n$ times in order to get the $n$ results
$$\omega_1,\omega_2,\ldots,\omega_n,$$
and so drawing a sample gives us the $n$-tuple
$$X(\omega_1),X(\omega_2),\ldots,X(\omega_n).$$
But even in this case, we could define a new space taking
$$\tilde\Omega=\Omega^n=\Omega \times \Omega \times \ldots \times \Omega \quad\text{($n$ times)},$$
with $\tilde {\mathcal A}$ as the product $\sigma$-algebra and $\tilde P$ according to the usual probability properties. In this way, performing the $n$ successive experiments represented by $(\Omega,\mathcal A,P)$ would be equivalent to performing just once the experiment represented by $(\tilde\Omega,\tilde{\mathcal A},\tilde P)$.