I understand, and ask not about, how to prove that you ought switch. Let $\Pr(✘)$ = probability that the unchosen doors have the prize (I chose the X mark to signify that you chose wrongly).
Please see the question in the title. Monty knows which door lacks the prize and must open it, but why exactly is $\Pr(✘)$ "reduced" to the lone unopened door?
The quotes beneath don't explicitly explain this "collapsing" of $\Pr(✘)$ . This Reddit comment
Another way to understand the solution is to consider the two original unchosen doors together. Instead of one door being opened and shown to be a losing door, an equivalent action is to combine the two unchosen doors into one since the player cannot choose the opened door[.]
refers to an older version of Wikipedia:
As Cecil Adams puts it (Adams 1990), "Monty is saying in effect: you can keep your one door or you can have the other two doors." The 2/3 chance of finding the car has not been changed by the opening of one of these doors because Monty, knowing the location of the car, is certain to reveal a goat. So the player's choice after the host opens a door is no different than if the host offered the player the option to switch from the original chosen door to the set of both remaining doors. The switch in this case clearly gives the player a 2/3 probability of choosing the car.
As Keith Devlin says (Devlin 2003), "By opening his door, Monty is saying to the contestant 'There are two doors you did not choose, and the probability that the prize is behind one of them is 2/3. I'll help you by using my knowledge of where the prize is to open one of those two doors to show you that it does not hide the prize. You can now take advantage of this additional information. Your choice of door A has a chance of 1 in 3 of being the winner. I have not changed that. But by eliminating door C, I have shown you that the probability that door B hides the prize is 2 in 3.'"
I first saw the idea that $\Pr(✘)$ "is now concentrated on that other door", on Reddit:
Imagine instead of 3 doors, there were 100 doors. You had a 1 in 100 chance of picking the door with the car behind it. Monty opens 98 doors to reveal 98 goats. So why should you switch? Well, the odds of you picking the car off the bat were 1 in 100. That means there is a 99% chance that the door you picked initially has a goat behind it. Monty has opened all of the other goat doors, meaning your odds are much better if you switch, because he eliminated all of the other goats in the problem except for one.