Let $E=\{\{\omega \} : \omega \in \Omega \}$.
$\sigma ( E) = \{ A \subseteq \Omega : A \ is \ countable \ or \ A^c \ is \ countable \} $ is a $\sigma$-algebra generated by the set $E$ i.e. the smallest $\sigma$-algebra containing $E$ (already proved).
Prove: $\sigma (E)$ is equal to partitive set of $\Omega$ if and only if $\Omega$ is a countable set.
One side: Suppose $\Omega$ is countable. $\sigma (E)$ contains all the sets that are countable or their complement is countable. That is true for every subset of a countable set, so it leads $\sigma (E)$ is a partitive set of $\Omega$.
Other side: please help