If the number of states is $N\ge 3$, then the answer is $1/(N-1)$, independent of the starting point and of $j$.
Setup: Let the states be $0,\dots, N-1$ and WLOG assume we start from $0\ne j$.
Let $I_j$ be the ``interval" consisting all elements in the cycle, except for $j$ and its two immediate neighbors, $j\pm 1 \mod N$.
We get to $j$ last if and only if we
- exit $I_j$,
and then
- If exiting $I_j$ from $j\pm 1 \mod N$, then we need to exit the interval consisting of all elements but $j$ from $j\mp 1 \mod N$.
The first event occurs with probability $1$, and, due to symmetry, the probability of the event on part 2. is independent of the past, and is equal to the probability that symmetric random walk on $Z$ starting from $1$ hits $N-1$ before hitting $0$. This, by a simple calculation (the probability as a function of the starting point satisfies a linear recurrence with boundary values), is equal to $1/(N-1)$.