This has been thoroughly studied in the paper "The Jordan Canonical Forms of complex orthogonal and skew-symmetric matrices" by Horn and Merino (1999) and also in Olga Ruff's master thesis "The Jordan Canonical Forms of complex orthogonal and skew-symmetric matrices: characterisation and examples" (2007). In particular, theorem 1.2.3 (pp. 31-32) of Ruff's thesis states that
An $n\times n$ complex matrix is similar to a complex orthogonal matrix if and only if its Jordan Canonical Form can be expressed as a direct sum of matrices of only the following three types:
(a) $J_k(\lambda)\oplus J_k(\lambda^{-1})$ for $\lambda\in\mathbb C\setminus\{0\}$ and any $k$,
(b) $J_k(1)$ for any odd $k$ and
(c) $J_k(-1)$ for any odd $k$.
(Note that when $\lambda=\pm1$, the matrix in (a) is just two copies of $J_k(\lambda)$. Hence case (a) implies that an even-sized Jordan block for $\lambda=\pm1$ must appear an even number of times, while (a), (b) and (c) together allows an odd-sized Jordan block for $\lambda=\pm1$ to appear any number of times.)
In particular, every nonzero complex number is an eigenvalue of some complex orthogonal matrix, and for each complex orthogonal matrix, all eigenvalues $\ne\pm1$ must occur in reciprocal pairs.