Nearly but not quite. Start with a simpler case e.g. two dice and you are trying to get at least one 6. What are the odds? A common naive answer is 2/6. However, this is obviously wrong, consider 3, 4, 5, 6, and 7 dice. With 6 dice, getting at least one 6 is likely but certain. With 7 dice, it is not more than certain.
The correct answer can be seen by listing all 36 ways that two dice could fall. You will see that only 11 out of 36 contain a 6 so the odds are only 11/36. The overcounting is due to one of the 36 cases being double 6.
Back to the lottery, this approach is not so practical but fortunately there is an alternative. It is easier to calculate the chances that you don't win with $n$ tickets.
Don't win with 1 ticket: $\frac{13999999}{14000000}$.
Don't win with 2 tickets: $(\frac{13999999}{14000000})^2$.
Don't win with 3 tickets: $(\frac{13999999}{14000000})^3$.
Don't win with n tickets: $(\frac{13999999}{14000000})^n$.
Subtract from 1 to get the odds of winning.
With a very low probability such as $\frac{1}{14000000}$, the first few will be very close to the naive answers. As $n$ gets bigger, the difference will become more obvious.
Thanks to comments by Losvos and TMM: note that I have accidentally assumed that each ticket is an independent random choice as would be typical with dice. If you are careful not to repeat your selections then the naive logic will be correct. Buy all possible 14000000 tickets and you are sure to win. However, it is very likely that you will win less than the cost of the tickets. Even if the jackpot is higher, due to rollovers, be aware that someone else might win and you will share the jackpot.