Let $X$ be a normed space, $X'$ be its continuous dual, and $X_w'$ be the weak-star version. Apparently, the dual of $X_w'$ is $X$. So the second dual of $X_w'$ should be $X'$. Since $X_w'$ and $X'$ have the same points, the canonical embedding from $X_w'$ to its second dual is onto, meaning that $X_w'$ is homeomorphic to $X'$.
Of course, $X_w'$ isn't the same as $X'$ in general, so I know the above argument is flawed. Can someone please point out my mistake(s)?