I assume that the OP wishes to match substrings of the form
abcm
where:
"cm" is a literal;
"cm" is not followed by a letter;
"b" is the string representation of a non-negative float or integer (e.g., "80" or "80.25", but not "08" or ".25"); and
"a" is a character other than "-", "+" and ".", unless "b" is at the beginning of the string, in which case "a" is an empty string.
If my assumptions are correct you could use the following regex to match b in abcm:
(?<![-+.\d])[1-9]\d*(?:\.\d+)?cm(?![a-zA-Z])
Demo
The regex engine performs the following operations:
(?<! # begin negative lookbehind
[-+.\d] # match '-', '+', '.' or a digit
) # end negative lookbehind
[1-9] # match digit other than zero
\d* # match 0+ digits
(?:\.\d+) # match '.' followed by 1+ digits in a non-cap grp
? # optionally match non-cap grp
cm # match 'cm'
(?![a-zA-Z]) # match a letter in a negative lookahead
If my assumptions about what is required are not correct it may be evident how my answer could be adjusted appropriately.