Since you tagged your question with WPF, I can tell you the way of doing it in WPF, you can validate if that can be reused in Windows phone 8 apps.
First, you can give x:Name to root element to which ViewModel is bind to. Say it's window, set x:Name on it and bind using ElementName.
<Window x:Name="myWindow">
...
<DataTemplate x:Key="template">
<StackPanel>
<TextBlock Text="{Binding Name}"/> <!-- From list item -->
<TextBlock Text="{Binding DataContext.MyViewModel.Country,
ElementName=myWindow }"/> <!-- From view model -->
</StackPanel>
</DataTemplate>
</Window>
Second, you can try using RelativeSource to travel Visual tree and get root element DataContext.
<DataTemplate x:Key="template">
<StackPanel>
<TextBlock Text="{Binding Name}"/> <!-- From list item -->
<TextBlock Text="{Binding DataContext.MyViewModel.Country,
RelativeSource={RelativeSource Mode=FindAncestor,
AncestorType=Window} }"/>
<!-- From view model -->
</StackPanel>
</DataTemplate>
Moreove, if ListBox is inheriting DataContext from root element (i.e. you haven't explicitly set DataContext on ListBox). You can use both approaches on ListBox as well in place of Window.
Note - As mentioned here, FindAncestor is not defined for Windows phone 8 but element name does work. So, try using first approach and it should work for you.