Notice that your sum is $2 \sum_k {k\choose 2} {m\choose k}$ (I am deliberately omitting the range for $k$; why?).
This suggests that we might consider the more general sum:
$$S_{m,l} := \sum_k {k\choose l} {m\choose k}$$
Here are my three favorite ways to compute this at a glance:
1) $S_{m,l}$ is the number of ways in which we can divide a group of $m$ people into three teams—A, B, and C—such that team C has exactly $l$ members.
2) $S_{m,l}$ is the coefficient of $x^l$ in $(1+(1+x))^m = (2+x)^m$.
3) $S_{m,l}$ is $\frac{1}{l!}$ times the $l^{\operatorname{th}}$ derivative of $(1+x)^m$, evaluated at $x=1$.
In any case, we observe: $$S_{m,l} = {m\choose l} 2^{m-l}$$
In particular, your sum is $2 S_{m,2} = 2 {m\choose 2} 2^{m-2} = m(m-1)2^{m-2}$.