An axiom system $\Sigma$ in $L$ is called contradiction-free or consistent if there is a formula $\varphi$ with $\Sigma \not\vdash \varphi$. (For even a single contradiction of the form $\varphi \land \neg \varphi$ would allow everything to be derived from $\Sigma$.)
Theorem: If $\Sigma := \Sigma \cup \{\varphi\}$ ($\Sigma$ is extended with the axiom $\varphi$) is consistent, then $\Sigma \not\vdash \neg \varphi$ and vice versa.
If $\Sigma$ contains the formula $\varphi$ and is consistent, then obviously $\neg \varphi$ cannot also follow from $\Sigma$, because from such a contradiction, it would be possible to derive everything in Hilbert's calculus via axiom xi ($(\varphi \wedge \neg \varphi) \to \psi$), making $\Sigma$ inconsistent, in contradiction to the assumption. And if $\Sigma \not\vdash \neg \varphi$, then $\Sigma$ would be consistent with $\varphi$, alone because not every formula is derivable. This would admittedly be more of a metamathematical idea for a proof; the proof in Hilbert's calculus would look more technical.
Is it true to call my proof metamathematical and distinguish it from a proof in the Hilbert-calculus? Feel also free to point out any mistake in the proof (it is more a sketch) itself.