We will use the following formulation of the uniform boundedness theorem.
Theorem 1. Let $X$ and $Y$ be normed spaces and $\mathcal{F} \subseteq \mathcal{L}(X,Y)$ a non-empty family of bounded linear operators from $X$ into $Y$. Suppose the set
\begin{equation}
\{x\in X : \{T(x) : T \in \mathcal{F} \} \text{ is bounded} \}
\end{equation}
contains a set of the second category in $X$. Then $\{T(x) : T \in \mathcal{F} \}$ is bounded for all $x\in X$. Moreover, the family $\mathcal{F}$ is uniformly bounded, that is, there exists some $M \geq 0$ such that $\|T\|_{\mathcal{L}(X,Y)} \leq M$ for all $T \in \mathcal{F}$.
The standard proof of Theorem 1 makes use of the Baire category theorem. You can see 5.13 of Real Analysis by Folland for a proof of the uniform boundedness theorem in the above formulation.
We will also use the following elementary result. A proof can be found in Theorem 6.14 of Real Analysis by Folland.
Lemma 1. Let $(X, \mathcal{A}, \mu )$ be a measure space. Let $p\in [1, \infty ]$ and let $p'$ denote the Hölder conjugate exponent of $p$. Let $g \colon X \to \mathbb{C}$ be measurable. Suppose the following conditions hold.
- The set $\{x\in X : g(x) \neq 0 \}$ is $\sigma$-finite.
- We have $fg \in L^{1}(X, \mu )$ for all $f\in \Sigma$, where $\Sigma$ denotes the collection of simple functions $u\colon X \to \mathbb{C}$ such that the set $\{x\in X : u(x) \neq 0\}$ has finite measure.
- The set
\begin{equation}
\Big\{ \Big| \int_{X} fg \, d\mu \, \Big| : f\in \Sigma \text{ and } \|f\|_{L^{p'}} = 1 \Big\} \tag{$*$}
\end{equation}
is bounded.
Then $g\in L^{p}(X, \mu )$ and the supremum of ($*$) is equal to $\|g\|_{L^{p}}$.
We now address the question.
Theorem. Let $p,q\in [1, \infty ]$ with $p < q$. Then $L^{q}[0,1]$ is of the first category in $(L^{p}[0,1], \|\cdot\|_{L^{p}})$.
Proof. Let $A$ denote the collection of simple functions $u\colon [0,1] \to \mathbb{C}$ such that $\|u\|_{L^{q'}} = 1$. For each $f\in A$ define $\phi_{f} \colon L^{p}[0,1] \to \mathbb{C}$ by $\phi_{f}(g) := \int_{[0,1]} fg$. Since $A \subseteq L^{p'}[0,1]$, it follows from the Hölder inequality that $A \subseteq \mathcal{L}(L^{p}[0,1], \mathbb{C})$.
Let $g\in L^{p}[0,1]$. We have
\begin{equation}
\{ \phi_{f}(g) : f\in A \} = \Big\{ \int_{[0,1]} fg : f\in A \Big\} . \tag{1}
\end{equation}
It follows from $(1)$, Lemma 1 and the Hölder inequality that
\begin{equation}
\{g\in L^{p}[0,1] : \{ \phi_{f}(g) : f\in A \} \text{ is bounded} \} = L^{q}[0,1]. \tag{2}
\end{equation}
Since $L^{q}[0,1] \neq L^{p}[0,1]$, we deduce from $(2)$ and Theorem 1 that $L^{q}[0,1]$ is of the first category in $L^{p}[0,1]$.