First, $\mathsf{ZF}$ and $\mathsf{ZFC}$ are classical theories, so they contain $\mathsf{LEM}$ as an axiom. If you want to talk about intuitionistic set theory, you should refer to the intuitionistic $\mathsf{ZF}$ or constructive $\mathsf{ZF}$, denoted by $\mathsf{IZF}$ and $\mathsf{CZF}$ respectively. I do not want to explain the difference between $\mathsf{IZF}$ and $\mathsf{CZF}$ and their historical origins; You should refer to the second section of my preprint.
Regarding the unprovable part of the de Morgan's law, it is known that it is equivalent to the weak excluded middle $\lnot P \lor\lnot\lnot P$. Of course, it does not mean constructive mathematicians do accept this rule; Rather, it is more likely that constructive systems will not accept the remaining part of de Morgan's law since it is too close to the full $\mathsf{LEM}$. Yes, it may make doing mathematics harder, but in some cases (like, Bishop-styled constructive analysis) it is not too hard.
There are bunch of models not satisfying the remaining part of the de Morgan's laws (or equivalently, the weak excluded middle). You may pick almost any intuitionistic model, like, the effective topos (a realizability topos for Kleene's first algebra, a PCA given by a universal Turing machine). If you don't like toposes, you may check McCarty's doctoral thesis in which the author presents a model of $\mathsf{IZF}$ that should be 'equivalent' to the effective topos.