Suppose $X$ is a scheme, and $\mathcal{F}$ be a locally free sheaf (mayn't be of finite rank).
Definition of reflexive is given here: https://stacks.math.columbia.edu/tag/0AVU
Note that in the definition of reflexive, they stacks project assumes $\mathcal{F}$ is coherent, and hence finite type. But for the definition of reflexive, we don't need $\mathcal{F}$ to be coherent.
I know if $\mathcal{F}$ be a locally free sheaf of finite rank, then it would be reflexive. But I don't know if this is true for any locally free sheaf. Any help would in proving or disapproving this would be appreciated.