Consider the extension $1 \to C_3 \to S_3 \to C_2 \to 1$. I am trying to see intuitively why the action induced by the conjugation action $C_2 \curvearrowright C_3$ on $H^{\bullet}(C_3, \mathbb{Z})$ is multiplication by $(-1)^m$ for $n = 2m$.
It suffices to consider $n=2$. I was able to verify the statement by considering the group action $C_2 \curvearrowright H^2(C_3, \mathbb{Z})$, where the action is given by:
$$(g\phi)(h_1,...,h_n) = g \phi(gh_1g^{-1}, ..., gh_ng^{-1}) = \phi(gh_1g^{-1}, ..., gh_ng^{-1})$$
as the action on $\mathbb{Z}$ is trivial. If $\phi$ is a ($2$-)cocycle, then by direct computation, we can show that $\phi(1, h) = \phi(h',1)$ for any $h, h'$. Then, letting $\psi = \phi(-, h_2)$, it follows that $\phi + g\phi = d^1(\psi)$ i.e. that $[\phi] = -[g\phi]$ in $H^n$.
I suppose that, in this instance, there are not too many possibilities for the action, so it would have been feasible to determine the map by exhaustion. But is there a way to see that this is the case without exhaustion -- should I find it obvious that the map is multiplication by $-1$?