This is probably an oversight, but it indeed seems that Glimm and Jaffe did not define what they meant by a polynomial function $\phi\mapsto A(\phi)$, on the the space of temperate distributions $\mathscr{S}'(\mathbb{R}^d)$, before they invoked this notion in Theorem 6.3.1. From the general context in the book, a reasonable guess is that they meant a finite linear combination of products of functions of the form $\phi\mapsto \phi(f)$ where $f$ is a test function in Schwartz space $\mathscr{S}(\mathbb{R}^d)$. This is what was already mentioned in the comment by Rhys. However, this is an ad hoc definition, and it might be worthwhile to recall the more canonical definition of a polynomial function on $\mathscr{S}'(\mathbb{R}^d)$, by first revisiting this notion in the simpler case of a finite dimensional vector space $V$, using a little bit of modern multilinear algebra.
The space of degree one homogeneous polynomial functions, is the dual space $V'$.
The space of degree $n$ homogeneous polynomial functions on $V$ is the symmetric power ${\rm Sym}^n(V')\subset (V')^{\otimes n}$. Finally, the space of polynomial functions is the direct sum $\bigoplus_{n\ge 0}{\rm Sym}^n(V')$.
Now, lets redo this with $V=\mathscr{S}'(\mathbb{R}^d)$.
The key remark is that $V'=(\mathscr{S}'(\mathbb{R}^d))'=\mathscr{S}(\mathbb{R}^d)$, because Schwartz space is reflexive. For this one needs to always use the canonical choice of topology, namely the strong dual topology, when taking duals of topological vector spaces, instead of the ad hoc but more popular weak-$\ast$ topology.
Then taking topological (completed) tensor products, the analogue of $(V')^{\otimes n}$ is $\mathscr{S}(\mathbb{R}^{nd})$. Finally, the correct notion of polynomial function is: functions of the form
$$
\phi\longmapsto \sum_{n=0}^N \langle \phi^{\otimes n}, f_n\rangle
$$
where $(x_1,\ldots,x_n)\mapsto f_n(x_1,\ldots,x_n)$ is a Schwartz function on $(\mathbb{R}^d)^n$, i.e., $f_n\in \mathscr{S}(\mathbb{R}^{nd})$. Here $\phi^{\otimes n}\in \mathscr{S}'(\mathbb{R}^{nd})$ is built using the notion of tensor product of Schwartz distributions.
Note that one can choose to require the $f_n$ to be symmetric or not, but it does not matter since they are paired with a distribution which is symmetric.
Also note that in the finite dimension case the two types of definitions are the same because tensors are finite sums of decomposable tensors. For $V=\mathscr{S}'(\mathbb{R}^d)$, this is not true, but the polynomial functions in my answer can be approximated by functions as in Glimm-Jaffe and the comment by Rhys.