Chebyshev first proved that there exist constants $a$, $b$ such that $$ a \frac{n}{\log n} < \pi(n) < b \frac{n}{ \log n}.$$ The proof is well understood, and relies on elementary techniques.
However, Sylvester extended this proof, and according to this website , the explicit bound holds with $b = 1.04423$ for large enough $n$. I would be grateful if someone could provide a proof of this claim, or a sketch of the methods used by Sylvester