Just a few words about rigor.
As said in the comment, the topology on $SO(3)$ should be the subsapce topology induced from the inclusion $$SO(3)\subset M_{3\times 3}(\mathbb R)\simeq \mathbb R^9$$
As a subspace, it's still Hausdorff. It's easy to see it's both closed and bounded, hence compact. Now given the explicit mapping from $S^3$ to $SO(3)\subset\mathbb R^9$ which is clearly continuous (all entries are just polynomials), and one can check that it's surjective. Therefore as both of $S^3$ and $SO(3)$ are compact Hausdorff, this is a quotient map.
(To drive the formula, we can combine the idea from the linked post and the Rodrigues' rotation formula. Maybe there is an easier way - such as using $SU(2)$ as the bridge mentioned in the comment, but anyway I won't bother here.)