Given is $e^x>x^\alpha,\forall x\ge0$, taking logarithm on both sides, we get $x>\alpha \log{x}$. Now if $0<x<1$, $\log{x}<0$, so if we divide by $\log{x}$ the inequality gets reversed: $\frac{x}{\log{x}} < \alpha$.
Thus, the value of $\alpha$ must be greater than the maximum value of $\frac{x}{\log{x}}$ in $(0,1)$, which is at $x=0$ and the maximum value in $(0,1)$ is $0$, as we can see from this graph. Thus $\alpha > 0$.
Now for the case when $x>0$, $\log{x}>0$, thus $\frac{x}{{\log}{x}}>\alpha$. In this case, $\alpha$ must be smaller than the minimum value of $\frac{x}{\log{x}}$ in $(1,\infty)$, which is at $x=e$ and the value of the minimum is $e$. Thus, $\alpha<e$.
Overall, we get that $0<\alpha<e$, such that $e^x>x^\alpha,\forall x>0$.