I see a remarkable answer about this question in Why is the Petersen graph no Cayley graph?.
In this proof. If $G=\mathbb{Z}_{10}$ and generator set is $C=\lbrace a,b,c\rbrace$, then one can find a 4-cycle in Cayley graph $X(G,C)$. The original word in above proof is “$a^{-1}b^{-1}ab$ gives a cycle of length 4”. But I have a little confusion about this. What’s $a^{-1}b^{-1}ab$ mean? A 4-cycle or others?
Petersen graph is undirected and has no loop, impilying that $C$ is inverse-closed and $0\notin C$. So, we may assume $b=-b$ and $a+c=0$. Consequently $0-a-(a+b)-b-0$ is an obvious 4-cycle.