First you notice that you have $$\tag10\leq I -A\leq I$$(the first inequality is $A\leq I$ and the second one is $A\geq0$). Next one shows that
$$\tag2
0\leq T\leq S\implies \|T\|\leq\|S\|.
$$
There are several ways to show this, none entirely straightforward. It's a bit easier when $S=I$.
When $S=I$ one can do, with $\|x\|=1$,
$$
\|Tx \|^2=\langle T^2x,x\rangle=\langle TT^{1/2}x,T^{1/2}x \rangle
\leq\langle T^{1/2}x,T^{1/2}x \rangle=\langle Tx,x\rangle\leq 1.
$$
One path to show $(2)$ in general is to use the fact that for a selfadjoint operator $T$,
$$
\|T\|=\sup\{|\langle Tx,x\rangle|: \|x \|=1\}.
$$
Then $\|T\|\leq\|S\|$ follows from
$$
\langle Tx,x\rangle\leq\langle Sx,x\rangle.
$$
Another path to show $(2)$ is to use the fact that if $0\leq T\leq S$ then there exists a contraction $C$ such that $T^{1/2}=CS^{1/2}$. For then you have, via the C$^*$-identity $\|X\|^2=\|X^*X\|$,
$$
\|T\|=\|T^{1/2}\|^2=\|CS^{1/2}\|^2\leq\|S^{1/2}\|^2=\|S\|.
$$
In the case $S=I$ another approach is to use functional calculus. The C$^*$-algebra generated by $T$ is isomorphic to $C(\sigma(T))$ in a way that $T$ gets mapped to the identity function. Then $(1)$ becomes the number inequality $0\leq 1-t\leq 1$ which easily implies $|1-t|\leq1$.