A group of order $75=3\cdot 5^2$ has a normal $5$-sylow subgroup $H_5$ and a sylow $3$-sylow subgroup $H_3$. As $H_3\cap H_5 = \{1\}$, we must have, by the recognition theorem, $$G=H_5H_3\simeq H_5\rtimes_{\varphi} H_3$$ with the map $$\varphi:H_3\to\operatorname{Aut}(H_5)(x\mapsto\varphi_x:y\mapsto xyx^{-1}).$$
Now $H_3\simeq \Bbb Z_3$. The semidirect product is non-abelian if $\varphi$ is not trivial, and it's easy to see if $H_5\simeq \Bbb Z_{25}$, $\varphi$ must be trivial. So it remains to examine the case $H_5\simeq \Bbb Z_5\times \Bbb Z_5$ with $\operatorname{Aut}(H_5) \simeq \operatorname{GL}_2(\Bbb Z_5).$
So we need all homomorphisms $$\varphi:\Bbb Z_3\to\operatorname{GL}_2(\Bbb Z_5),$$ in other words we need to find all order $3$ elements in $\operatorname{GL}_2(\Bbb Z_5)$. Definitely there will be more than one order $3$ elements in $\operatorname{GL}_2(\Bbb Z_5)$. So how do I prove that such non-trivial $\varphi$ is actually unique?