Given a domain $\Omega \subset \mathbb{R}^n$, it is well-known that the dual space of the Sobolev space $W_0^{1,2}(\Omega)$ (also denoted by $H^1_0(\Omega)$ by many people) is, by definition, the space $W^{-1,2}(\Omega)$. Also, since $W_0^{1,2}(\Omega)$ is a Hilbert space; Therefore its dual is isomorphic to itself, by the Riesz representation theorem. Thus there is an isomorphism, say $\mathcal {E}$, between $W_0^{1,2}(\Omega)$ and $W^{-1,2}(\Omega)$.
One such isomorphism that interest to me is the one induced by an elliptic operator. Let $L= - \mathrm{div} (A \nabla)$ be an uniformly elliptic operator; that is, $\lambda |\xi|^2 \leq \langle A(X) \xi, \xi \rangle \leq \lambda^{-1} |\xi|^2$ for some $\lambda >0$, all $X \in \Omega$ and all non-zero $\xi \in \mathbb{R}^n$. Then $L$ would induce a duality pair $\langle u,v \rangle$ for $u \in W_0^{1,2}(\Omega)$ and $v \in W^{-1,2}(\Omega)$, and hence an isomorphism, say $\mathcal{E}_L$, between the two mentioned spaces.
I want to know what is the true definition of this duality pair, and the resulting isomorphism. It seems that, this maybe in the connected to some elliptic PDE's. Given $v \in W^{-1,2}(\overline{\Omega})$, there exists a unique solution $u \in W_0^{1,2}(\Omega)$ to the elliptic equation
$ \begin{cases} u+Lu=0,& \hskip 2mm \text {on} \hskip 2mm \Omega \\ u=v,& \hskip 2mm \text {on} \hskip 2mm \partial \Omega \end{cases}.$
But I'm not sure if this the right formulation of the mapping $v \mapsto u$; and, even this is true, what is the true definition of duality pairing $\langle u,v \rangle$ and the associated isomorphism $\mathcal{E}_L$ in this case.
Any reference would be appreciated. There is a related question here (especially example 3 therein).