Purely historical/conventional. There is no technical reason to exclude $0$-ary relation symbols (proposition symbols).
I can think of two reasons why model theorists tend to ignore proposition symbols. First, model theorists care about mathematical structures, like groups, graphs, ordered fields, etc, and propositions are typically not part of the data of these kinds of structures. Second, model theorists tend to be interested in models of complete theories, and a complete theory will decide the truth value of all proposition symbols. This means all models agree on the interpretations of all proposition symbols, so from this point of view they are irrelevant.