I came across this problem studying for a qualifier, and I'm pretty stumped outside of the more obvious steps to take. Here is what I've done so far, which isn't much at all.
Let $A_4$ act on a set $S$ transitively. Then $A_{4} \cdot x = S$ for every $x \in S$. The trivial action implies $A_4 \cdot x = \{x\}$, so one possibility is $\text{card}(S)=1$. I also know that $A_4$ has various subgroups, one normal of order $4$, several of order $2$ and of order $3$, but I'm not sure how this helps.
I also know that any set $S$ which $A_4$ acts on is nessiarily partitioned into by orbits $S = \bigcup_{x} \text{orb}(x)$ with $\sum_{x} \text{card}(\text{orb}(x)) = \sum_{x} [A_4:(A_{4})_x]$ by the orbit stabilizer theorem, where $x$ ranges over a collection of distinct orbit representatives, but I'm not sure where to go from here.
Any help would be appreciated. Thank you.