Let
- $\Theta$ be a closed $d$-manifold (and hence a metric space with Borel-$\sigma$-algebra $\Sigma \subset 2^\Theta$),
- $S^d$ the set of real symmetric $d \times d$ matrices, which we can identify with the vector space $\mathbb{R}^{\frac{d(d + 1)}{2}}$,
- $M(\Theta; S^d)$ be space of Borel vector measures on $(\Theta, \Sigma)$ with values in $S^d$,
- $C(\Theta; S^d)$ the space of continuous functions from $\Theta$ to $S^d$. (If I should instead consider compactly supported continuous functions, then this is fine, too.)
I am trying to find a duality statement along the lines of $[M(\Theta; S^d)]^* \cong C(\Theta; S^d)$, where $^*$ denotes the dual vector space.
For $d = 1$ I think I know how a isometric isomorphism $\Psi \colon [M(\Theta; S^d)]^* \to C(\Theta; S^d)$ and its inverse looks like, but I am not sure how to generalise this result and its proof to higher dimensions. It should be relatively straightforward since $S^d$ is finite-dimensional, so we should be able to "copy the one-dimensional procedure componentwise", see e.g. the comment on this highly related question or this pretty similar question, but I don't know how to do that.
For $d = 1$ I have the following: consider $$ \Psi: [M(\Theta, \mathbb R)]^* \to C(\Theta; \mathbb R), \qquad Z \mapsto \big(\theta \mapsto Z(\delta_{\theta})\big), $$ where $\delta_{\theta}(A) := \begin{cases} 1, & \text{if } \theta \in A, \\ 0, &\text{else.}\end{cases}$ is the Dirac measure at $\theta \in \Theta$ for $A \in \Sigma$.
This map is clearly linear. It is also injective: for $Z_1, Z_2 \in [M(\Theta; \mathbb R)]^*$ we have $\Psi(Z_1) = \Psi(Z_2)$ if and only if $Z_1(\delta_{\theta}) = Z_2(\delta_{\theta})$ for all $\theta \in \Theta$. By the linearity of $Z_1$ and $Z_2$ this implies that $Z_1$ agrees with $Z_2$ on any spike train $\sum_{k = 1}^{n} a_k \delta_{\tilde{\theta}_k}$ for $n \in \mathbb N$, $(a_k)_{k = 1}^{n} \subset \mathbb R$ and $(\tilde{\theta}_k)_{k = 1}^{n} \subset \Theta$. By the continuity of $Z_1$ and $Z_2$ and the density of those spike trains in $M(\Theta; \mathbb R)$, we can conclude that $Z_1 = Z_2$.
As inverse I suggest $$ \Psi^{-1}(f) := \left(\mu \mapsto \int_{\Theta} f(\theta) \; \text{d}\mu(\theta) \right). $$ Indeed, for $f \in C(\Theta; \mathbb R)$ we have $$ \Psi(\Psi^{-1}(f)) = \Psi\left(\mu \mapsto \int_{\Theta} f(\theta) \; \text{d}\mu(\theta) \right) = \left( \tilde{\theta} \mapsto \int_{\Theta} f(\theta) \; \text{d}\delta_{\tilde{\theta}}(\theta\right) = f. $$ Furthermore, for $Z \in [M(\Theta; \mathbb R)]^*$ we have $$ \Psi^{-1}(\Psi(Z)) = \Psi^{-1}\left(\theta \mapsto Z(\delta_{\theta})\right) = \left( \mu \mapsto \int_{\Theta} Z(\delta_{\theta}) \;\text{d}\mu(\theta) \right). $$ Due to the linearity of $Z$ we have for any spike train as above $$ \big[\Psi^{-1}(\Psi(Z))\big]\left(\sum_{k = 1}^{n} a_k \delta_{\tilde{\theta}_k} \right) = \sum_{k = 1}^{n} a_k Z(\delta_{\tilde{\theta}_k}) = Z \left(\sum_{k = 1}^{n} a_k \delta_{\tilde{\theta}_k} \right). $$ Hence by continuity of $Z$ and the density of the spike trains we conclude $\Psi^{-1}(\Psi(Z)) = Z$.
What are the higher-dimensional analogues of $\Psi$ and $\Psi^{-1}$?
I tried $\Psi(Z) := \big(\theta \mapsto Z(P \delta_{\theta})\big)$, where $P = \text{id}_{d \times d} \in S^d$ and $\Psi^{-1}(f) := \left( \mu \mapsto \text{tr}\left( \int_{\Theta} f(\theta) \; \text{d}\mu(\theta)\right)\right)$, but they don't seem to fulfil either $\Psi \circ \Psi^{-1} = \text{id}_{C(\Theta; S^d)}$ nor $\Psi^{-1} \circ \Psi = \text{id}_{[M(\Theta; S^d)]^*}$.
Update
When equipping $M(\Theta; S^d)$ with the (strong) generalised total variation norm, then by Singer's representation theorem we have the opposite duality $[C(\Theta; S^d)]^* \cong M(\Theta; S^d)$ via the dual pairing $$ \langle \phi, u \rangle_{C(\Theta; S^d) \times M(\Theta; S^d)} = \int_{\Theta} \langle \phi(\theta), u'(\theta) \rangle_{S^d} \; \text{d}| u |(\theta), $$ where $| u | \in M(\Theta; [0, \infty))$ is the total variation measure of $u$ and $u'$ is the Radon-Nikodym derivative of $u$ with respect to $| u |$.
Hence we only have to figure out how $| u |$ and $u'$ look in this specific case. If $u = \sum_{k = 1}^{N} P_k \delta_{\{ \theta_k \}}$, we have $$ | u | = \sum_{k = 1}^{N} \| P_k \|_{S^d} \delta_{\{ \theta_k \}} \qquad \text{and} \qquad u'(\theta_k) = \frac{1}{\| P_k \|_{S^d}} P_k, $$ so that $$ \langle \phi, u \rangle_{C(\Theta; S^d) \times M(\Theta; S^d)} = \sum_{k = 1}^{N} \text{tr}\big(P_k \phi(\theta_k)\big). $$