We can actually prove mathematically, that there is no possibility to choose representatives that make the evaluation functionals well-defined and continuous.
Suppose there is a way to choose a function for each equivalence class such
that the evaluation functionals $\delta_x$ become well defined and continuous.
For each number $r\in[0,1]$, consider the function
$$
g_r(x)
= \begin{cases} 0 & :\; x < r \\ 1&:\; x \ge r. \end{cases}
$$
Let us denote by $f_r$ the chosen representative of $g_r$.
For each $r$, let $A_r\subset [0,1]$ be a set of measure zero
such that $f_r=g_r$ outside of $A_r$.
We define
$$
A_{\Bbb Q} := \bigcup_{q\in\Bbb Q\cap [0,1]} A_q.
$$
The set $A_{\Bbb Q}$ is still a set of measure zero (due to the countability of the rationals),
and for all rational $q\in[0,1]$ we have $f_q=g_q$ outside of $A_{\Bbb Q}$.
Let $x\in(0,1)$ be a point outside of $A_{\Bbb Q}$ (such a point must exist
because $A_{\Bbb Q}$ has measure zero).
Let us also choose two rational monotone approximations of $x$,
$q_n\nearrow x$ from below and $p_n\searrow x$ from above.
Note that we have $f_{q_n}(x) = g_{q_n}(x)=1$
and $f_{p_n}(x)=g_{p_n}(x)=0$ for all $n\in \Bbb N$.
One can also easily show that $f_{p_n} \to f_x$
and $f_{q_n}\to f_x$ in the $L^2[0,1]$ norm.
If $\delta_x$ was continuous, this would imply
$$
0 = f_{p_n}(x) = \delta_x(f_{p_n}) \to \delta_x(f_x) = f_x(x)
$$
and
$$
1 = f_{q_n}(x) = \delta_x(f_{q_n}) \to \delta_x(f_x) = f_x(x).
$$
This, however, is a contradiction.
some remarks/intuitions/ideas:
As mentioned in the comment below, picking a fixed point $x$ like $x=1/2$
a-priori and then showing that $\delta_x$ is discontinuous cannot work,
because the representatives can be chosen such that they all have the same value at $x$.
Because you do not know a-priori, which point $x$ to look at,
we need to study a larger class of functions.
This class should have two properties: First, it should be only countable,
(to allow for the trick with the countable union of sets of measure zero).
Second, there should be enough functions in this class so that we can
potentially "create problems" at many points in $[0,1]$.
The class of functions of $g_q$ for rational $q$ satisfies these properties.