Although the comments address the question, I thought it might be useful to give an answer that explicitly links to the relevant parts of Neukirch's book. From corollary (2.12) in Chapter III, almost all prime ideals $\mathfrak{p}$ of $K$ are unramified in $L$, and for those $\mathfrak{p}$, $L_\mathfrak{P}|K_\mathfrak{p}$ is unramified for all places $\mathfrak{P}|\mathfrak{p}$. Then for these extensions $L_\mathfrak{P}|K_\mathfrak{p}$, if $\alpha_\mathfrak{p} \in K_\mathfrak{p}$ is a unit, then by proposition (6.2) in Chapter IV and theorem (1.1) in Chapter V it follows that $\alpha_\mathfrak{p} = N_{L_\mathfrak{P}|K_\mathfrak{p}}(y)$ for $y \in L_\mathfrak{P}$, in fact $y \in U_{L_\mathfrak{P}}$ ( Or use the (1.2) Corollary in Chapter V ). So from the definition of norm residue symbol on page 302, $(\alpha_\mathfrak{p}, L_\mathfrak{P}|K_\mathfrak{p}) = 1$ ( $\because$ $( \ ,L_\mathfrak{P}|K_\mathfrak{p} ) $ has kernel $N_{L_{\mathfrak{P}}|K_{\mathfrak{p}}}L_{\mathfrak{P}}^{*}$ ).
In case it's not clear that $\mathfrak{p}$ unramified in $L$ means $L_\mathfrak{P}|K_\mathfrak{p}$ unramified: the first indented equation on page 165 is $e_w = (w(L^*) : v(K^*))$. Since $\mathfrak{p}$ is unramified in $L$, $v_\mathfrak{p}(K^*) = v_\mathfrak{P}(L^*)$. From the third indented equation on page 126, $v_\mathfrak{p}(K_\mathfrak{p}^*) = v_\mathfrak{p}(K^*) = v_\mathfrak{P}(L^*) = v_\mathfrak{P}(L_{\mathfrak{P}}^*)$ so $L_{\mathfrak{P}}|K_\mathfrak{p}$ unramified.
This is true no matter what $\mathfrak{P}|\mathfrak{p}$ is chosen.