If I understand well $V=L^k$, where $L=\mathbb F[X]/(p)$ is a field. On $V$ you define a multiplication by $$(a_0,a_1,\dots,a_{k-1})(b_0,b_1,\dots,b_{k-1})=(a_0b_0,a_0b_1+a_1b_0,\dots,a_0b_{k-1}+\cdots+a_{k-1}b_0).$$
It's easy to see that $V\simeq L[Y]/(Y^k)$ and thus your problem reduces to the following:
Let $\mathbb F$ be a field and $p\in\mathbb F[X]$ irreducible. Set $L=\mathbb F[X]/(p)$. Is it true that $L[Y]/(Y^k)$ is isomorphic to $\mathbb F[X]/(p^k)$?
Denote $L$ by $\mathbb F(t)$, where $t$ is the residue class of $X$ modulo $(p)$. (Obviously $p(t)=0$.) I'll prove that
$$L[Y]/(Y^k)\text{ is isomorphic to } \mathbb F[X]/(p^k)$$
whenever $p'(t)\neq 0$. (This happens, for instance, if the characteristic of $\mathbb F$ is $0$.)
Define a ring homomorphism $\varphi:\mathbb F[X]\to L[Y]/(Y^k)$ by sending $X$ to $y+t$, where $y$ denotes the residue class of $Y$ modulo $(Y^k)$. We have $\varphi(p(X))=p(y+t)=p(t)+yh(y)$, $h$ being a polynomial with coefficients in $L$ and having the property that $h(0)=p'(t)$. Since $p(t)=0$ we get $\varphi(p(X))=yh(y)$ and using that $y^k=0$ we obtain $\varphi(p^k(X))=0$, that is, $p^k(X)\in\ker\varphi$. But $\ker\varphi$ is a principal ideal (of $\mathbb F[X]$), so $\ker\varphi=(f(X))$ for some $f\in\mathbb F[X]$. Since $f(X)\mid p^k(X)$ we must have $f(X)=p^i(X)$ for $1\le i\le k$. Suppose $i<k$. Then $\varphi(p^i(X))=0$ which is equivalent to $y^ih^i(y)=0$, that is, $Y^ih^i(Y)\in(Y^k)$. We thus get $Y\mid h(Y)$, a contradiction (with $h(0)\neq 0$). As a consequence we have proved that $\ker\varphi=(p^k(X))$. It remains to prove that $\varphi$ is surjective. But this follows easily observing that $\varphi$ is a homomorphism of $\mathbb F$-vector spaces of the same dimension (equal to $k\deg p$).