The definition of countable additivity says that $P ( \bigcup_{n = 1}^{\infty} A_{n}) = \sum_{n = 1}^{\infty} P ( A_{n} )$ whenever $ A_{1}, A_{2}, \dots $ is a sequence of disjoint sets in the relevant sigma algebra.
Assuming countable addivity, let's prove finite additivity, which says that $P ( \bigcup_{n = 1}^{N} A_{n}) = \sum_{n = 1}^{N} P ( A_{n} )$ whenever $ A_{1}, A_{2}, \dots A_{N} $ is a sequence of disjoint sets in the relevant sigma algebra. Given $ A_{1}, A_{2}, \dots A_{N} $, we note that $$\bigcup_{n=1}^{N}A_{n} = A_{1} \cup A_{2} \cup \cdots \cup A_{N} = A_{1} \cup A_{2} \cup \cdots \cup A_{N} \cup \emptyset \cup \emptyset \cup \cdots.$$
The point of including all those empty sets in the union above is to obtain an infinite sequence of disjoint sets (since the empty set is disjoint from everything) so we can apply countable additivity. Doing so yields
$$
\begin{align*}
P (A_{1} \cup A_{2} \cup \cdots \cup A_{N}) &= P(A_{1} \cup A_{2} \cup \cdots \cup A_{N} \cup \emptyset \cup \emptyset \cup \cdots) \\
&= P(A_{1}) + P(A_{2}) + \cdots + P(A_{N}) + P(\emptyset) + P(\emptyset) + \cdots \\
&= P(A_{1}) + P(A_{2}) + \cdots + P(A_{N}) + 0 + 0 + \cdots \\
&= P(A_{1}) + P(A_{2}) + \cdots + P(A_{N}).
\end{align*}
$$
Since the sequence $A_{1}, A_{2}, \ldots, A_{N}$ was arbitary, we're done.