I am supporter of having formal definitions in mathematics. Only having them, then I understand words "faster", "tends", "grows" etc. So exact definition, taking non negative case, is:
$$O(g) = \left\lbrace f:\exists C > 0, \exists N \in \mathbb{N}, \forall n (n > N \& n \in \mathbb{N}) (f(n) \leqslant C \cdot g(n)) \right\rbrace $$
So, when we want to prove, that some function $\phi \in O(g)$, we need to find two constants $C, N$.
In your case, if you want to show, that some function is element of set $O\left(\dfrac{\log n}n\right)$, for example $\alpha_n=\frac{100}{n}$, you should solve inequality:
$$\frac{100}{n} \leqslant C \cdot\dfrac{\log n}n$$ and show, that it holds for $n>N$, for some $N \in \mathbb{N}$. In example we can take $N= \left \lceil e^{\frac{100}{C}} \right \rceil$.
As to your questions, then we have some standard properties for big-$O$
$$O(f) + O(g) = O(f+g)$$
$$C \cdot O(f) = O(C \cdot f)= O(f)$$
for exact proof you can see Arithmetic rules for big O notation, little o notation and so on...