Let $G$ be nonempty, open and connected.
(1) Assume $G$ is simply connected.
Assume $\mathbb C\setminus G=K\cup A$, $K$ compact, $A$ closed, $K\cap A=\emptyset$.
Note that $A\cup\{\infty\}$ is closed in $\overline{\mathbb C}$ and by compactness $K$ is closed in $\overline{\mathbb C}$. Thus via $\overline{\mathbb C}\setminus G=(A\cup\{\infty\})\cup K$ we have written the complement of $G$ as disjoint union of two closed sets. By connectednes of $\overline{\mathbb C}\setminus G$, one of them must be empty, and that can only mean $K=\emptyset$.
(2) Assume property 1 holds.
Assume $B$ is a (nonempty) bounded component of $\mathbb C\setminus G$.
Then the closure $K$ of $B$ is compact and is still disjoint to $G$.
Since $B$ is a component, $A:=\mathbb C\setminus G\setminus K$ is closed and we have $A\cap K=\emptyset$. By property 1, $K=\emptyset$, contradiction.
(3) Assume property 2 holds.
Write $\overline{\mathbb C}\setminus G=A\cap A'$ with $A,A'$ closed and disjoint. Wlog. $\infty\in A'$. Then $A$ is bounded. As $\mathbb C\setminus G$ has no bounded components, $A$ must be empty. Hence $\overline{\mathbb C}\setminus G$ is connected.