Given that the infinitude of Sophie Germain primes is still only conjectural, it's hopeless here to prove that one formula gives a better estimate, asymptotically, than another. However, we can discuss the relationships of the various formulas and how they relate to current counts of the Sophie Germain primes.
The main thing we can prove is the following: For $n\ge7$, we have
$${n\over\ln n\ln2n}\lt{n\over(\ln n)^2}\lt\int_2^n{dt\over\ln t\ln2t}$$
The first inequality is actually true for $n\ge2$, since $\ln2n\gt\ln n$ for all $n\gt1$. The second inequality needs to be checked for $n=7$ (it turns out the inequality points the other way for $n\le6$), after which we can show that
$$f(x)=\int_2^x{dt\over\ln t\ln2t}-{x\over(\ln x)^2}$$
is an increasing function by computing its derivative,
$$f'(x)={1\over\ln x\ln2x}-{1\over(\ln x)^2}+{2\over(\ln x)^3}$$
and showing that $f'(x)\ge0$ for all $x\ge7$. We do this by noting that, since $\ln2x$, $\ln x$, and $\ln x/2$ are all positive when $x\ge7$, we have
$$\begin{align}
f'(x)
&={(\ln x)^2-(\ln x)(\ln2x)+2\ln2x\over(\ln x)^3\ln2x}\\
&\gt{(\ln x)^2-(\ln x)(\ln2x)+\ln2\ln2x\over(\ln x)^3\ln2x}\\
&={(\ln x)^2-(\ln x/2)(\ln2x)\over(\ln x)^3\ln2x}\\
&\ge{(\ln x)^2-\displaystyle\left(\ln x/2+\ln2x\over2 \right)^2\over(\ln x)^3\ln2x}\\
&={(\ln x)^2-\displaystyle\left(\ln x^2\over2 \right)^2\over(\ln x)^3\ln2x}\\
&={(\ln x)^2-(\ln x)^2\over(\ln x)^3\ln2x}\\
&=0
\end{align}$$
where the key step invokes the Arithmetic-Geometric Mean inequality $\sqrt{ab}\le{a+b\over2}$ if $a,b\ge0$. (This is why we noted that $\ln x/2$ is positive for $n\ge7$.)
Now experimentally, the integral (multiplied by $2C$) seems to give a surprisingly accurate approximation to the actual count of Sophie Germain primes, $\pi_{SG}(n)$, while the simple fraction $n/(\ln n)^2$ seems to systematically undercount them. For example, for $n=10^{14}$, we have (in decreasing numerical order)
$$\begin{align}
2C\int_2^n{dt\over\ln t\ln2t}&\approx132822400531\\
\pi_{SG}(n)&=132822315652\\
2C{n\over(\ln n)^2}&\approx127055347336\\
2C{n\over\ln n\ln2n}&\approx124380891673
\end{align}$$
where the exact value is take from the OEIS sequence A092816. Other comparisons for powers of $10$ from $10^3$ to $10^{11}$ can be found on page 12 in Chris Caldwell's paper, "An Amazing Prime Heuristic." They all show $2Cn/(\ln n)^2$ giving a substantial undercount to $\pi_{SG}(n)$, while the integral sometimes undercounts and sometimes overcounts, but always gives a better approximation.
If that relationship persists, then changing $n/(\ln n)^2$ to $n/(\ln n\ln2n)$ will not help. On the other hand, if the conjectured infinitude of Sophie Germain primes is wrong, then $2Cn/(\ln n\ln2n)$ would, asymptotically, be the closest of the three "estimates," but only because it tends to infinity more slowly than the other expressions.