This is related to an Lemma 7.34 of Brian Hall, Lie group, Lie Algebra and Representations chpt 7.
Lemma 7.34: Let $K$ be a compact matrix lie group with non-commutative lie algebra. Then real lie algebra $k$ of $K$ cannot have complex structure(i.e. $\phi:g\to k$ is a lie algebra homomorphism with $g=l_C$ as complexification of some real lie algebra $l$ coming from some reductive lie group $L$. $\phi\circ(i\cdot)\circ\phi^{-1}$ induces complex multiplication on $k$.)
Since this complex structure does not say integrability condition, I would call this complex structure as almost complex structure.
$\textbf{Q:}$ It seems that in order to have complex structure on lie algebra, I need either commutative lie algebra or non-compact matrix lie group. What will guarantee existence of complex structure on a lie algebra? I would expect this complex structure pulls back by exponential to lie group and generate global trivialization of tangent bundle via left or right invariant vector field.(In particular, this will result in global splitting of complexified tangent bundle of lie group.)
$\textbf{Q':}$ Is there any intuitive reason to expect for compact non-commutative lie group's lie algebra not having the complex structure?