I am quite certain that $2\binom{d}{k} \le \binom{2d}{k}$ holds for every positive integers $k,d$, where $1 \le k \le d$.
Is there a simple proof? A combinatorial proof ?
An immediate combinatorial argument gives $2\binom{d}{k} \le \binom{2d}{2k}$, as the LHS corresponds to choosing $k$ elements out of $d$, and then choosing additional $k$ elements out of a distinct new set of $d$ elements. The RHS correspond to an "unconstrained" choice of $2k$ out of $2d$.
(I checked the cases $k=1,d$, and various other examples with "small numbers". For "large" $d$ the asymptotics of the binomial coefficients seems compatible with this inequality).