Recall that $H_1(T^2)$ is $\mathbb Z^2$, and is spanned by the class of the simplices $f_1$ and $f_2$, and in fact your map is coming from a pairing $\Omega^*(T^2) \otimes C_*(T^2,\mathbb R)\to\mathbb R$ such that $\langle \omega,\sigma\rangle = \int_\sigma \omega$. This is the same as the corresponding map $\Omega^*(T^2)\to C^*(T^2,\mathbb R)$, and what your question is claiming is that this is an isomorphism on cohomology, that is, a quasi-isomorphism. One can actually consider this map for any manifold $X$, let us call it $r_X$, the de Rham pairing.
Now something remarkable about $r_X$ this is that it is compatible with, for example, the Mayer-Vietoris sequence, in the sense that if $U,V$ are open and cover $X$, then the following diagram commutes
$$\require{AMScd}
\begin{CD} 0@>>>\Omega^*(X) @>>> \Omega^*(U)\oplus \Omega^*(V) @>>> \Omega(U\cap V) @>>> 0\\ {} @VVr_XV @VV{r_U\oplus r_V} V @VV{r_{U\cap V}}V\\
0 @>>> C^*(X) @>>> C^*(U)\oplus C^*(V) @>>> C^*(U\cap V) @>>> 0 \end{CD}
$$
It follows that if $r_X$ is a quasi-isomorphism for $U,V$ and $U\cap V$, it is an isomorphism. Indeed, this is a statement of homological algebra and follows from the so-called 5 lemma applied to the "infinite staircase" diagram obtained by lookin at the long exact sequences of the two Mayer-Vietoris sequences above.
Now you can cover the torus $T^2$ by two open sets $U$ and $V$ which
are homotopic to the $1$-sphere, and whose intersection is a disjoint union of two $1$-spheres. Hence, proving it for the $1$-sphere suffices.
In this case you know that $H^*_{dR}(S^1)$ is spanned by $1$ and an angle form $d\theta$,
and that $H_*(S^1)$ is spanned by, more or less, the identity $S^1\to S^1$. Then the induced by on homology is simply the isomorphism $\mathbb R\otimes\mathbb R\to\mathbb R$,
so you get what you wanted.