Hopefully you can already prove:
The center of a ring is a ring, in fact, a commutative ring.
Furthermore, if $D$ is a division ring, then for all $x\in Z(D)$, if $x\neq 0$, then $x^{-1}$ exists somewhere in $D$.
Now to show the commutative ring $Z(D)$ is a field, you'd have to show that $x^{-1}\in Z(D)$, because inverses are unique, and uniqueness of inverses in a division ring means you only have that candidate for the inverse in $Z(D)$.
So, the task is clear: if $0\neq x\in Z(D)$, prove $x^{-1}\in Z(D)$.
To prove a nonzero element $a$ commutes with all nonzero elements $b$, you can just check that $a^{-1}ba=b$ for all $b$.
Well, what do you think about $(x^{-1})^{-1}bx^{-1}=xbx^{-1}$?