Given $n > 1$, it's obvious that $$\frac{2^n - 1}{2^n} = \sum_{i = 1}^n \frac{1}{2^i}.$$
For example, $$\frac{15}{16} = \frac{1}{2} + \frac{1}{4} + \frac{1}{8} + \frac{1}{16}.$$ That's not the answer we'd get using the greedy algorithm, since after taking one half, it would take one third instead of one quarter: $$\frac{15}{16} = \frac{1}{2} + \frac{1}{3} + \frac{1}{10} + \frac{1}{240}.$$
That last denominator is a little larger than I'd like, but it's still just four fractions.
My main question is: does the greedy algorithm ever give more fractions than some other algorithm?
Maybe if we require the fractions to be distinct, e.g., in Egyptian fractions with very large denominators, Mr. Santos gives $$\frac{5}{31} = \frac1 7 + \frac 1 {55} + \frac 1 {3\,979} + \frac 1 {23\,744\,683} + \frac 1 {1\,127\,619\,917\,796\,295},$$ which is preferable to $$\frac{5}{31} = 5 \times \frac{1}{31}$$ only because of the distinct fraction requirement.
Then if the... sorry, my ride to vote is here, and then dinner